Comparison of the calculus body properties of calcined ginger nuts as rock and soil cultural relics reinforcement materials before and after ultrafining with quartz sand
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(1. Conservation Research Institute, Dunhuang Academy, Jiuquan 736200, China;2. National Research Center for Conservation of Ancient Wall Paintings and Earthen Sites (Dunhuang Academy), Jiuquan 736200, China;3. Key Scientific Research Base for Conservation of Ancient Wall Paintings (Dunhuang Academy), National Cultural Heritage Administration, Jiuquan 736200, China;4. Technical Service Center of Cultural Relic Conservation, Dunhuang Academy, Lanzhou 730030, China;5. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;6. Gansu Mogao Grottoes Cultural Heritage Protection Design Consulting Co., Ltd., Jiuquan 736200, China)

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    Abstract:

    The comparative tests of various properties of the calculus body of calcined ginger nuts before and after ultrafining with quartz sand were carried out. The structure, composition and morphology were analyzed using Fourier transform infrared spectrometry, X-ray diffraction and scanning electron microscopy. The applicability of the ultrafine powder of calcined ginger nuts in the process of reinforcing rock and soil cultural relics is discussed. The results show that, compared with normal calcined ginger nuts, the peaks of SiO2 in the calculus body of calcined ginger nuts after ultrafining were weakened, and the those of CaCO3 and Ca2Al2SiO7·nH2O were enhanced and sharpened, indicating that ultrafining was beneficial to the carbonization of Ca(OH)2 and the hydration of SiO2 and β-CaSiO3. The hydration ratio, condensation time, shrinkage rate, moisture content and wave velocity of the calculus body after ultrafining were improved, and early compressive strength and flexural strength were increased. The water resistance, freeze-thaw resistance, stability and alkaline resistance of the calculus body after ultrafining were significantly improved. The calculus body after ultrafining had better adhesion and compatibility with tuff and red sandstone. In brief, ultrafining has not only retained the advantages of normal calcined ginger nuts but also given full play to the potential cementation properties of calcined ginger nuts. Therefore, the use of calcined ginger nuts after ultrafining is more suitable for the conservation and reinforcement of rock and soil cultural relics.

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History
  • Received:November 27,2023
  • Revised:September 21,2024
  • Adopted:
  • Online: May 15,2025
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