中国传统血料灰浆的应用历史和科学性
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(1.浙江大学 文物与博物馆学系,浙江 杭州,310027;;2.浙江工业大学 化学工程与材料学院,浙江 杭州,310014)

作者简介:

张坤,(1989—),女,硕士研究生,研究方向:文物保护:Email:nvzhangkun@zju.edu.cn

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国家科技支撑计划资助(2012BAK14B05);国家文物局“指南针计划”专项资助(20111806)


The application history and scientific nature of bloodbased materials in traditional Chinese mortar
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(1.Department of Cultural Heritage and Museology, Zhejiang University, Hangzhou 310027, China; ;2.Department of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310014, China)

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    摘要:

    血料灰浆是中国古代建筑灰浆的重要代表作之一,体现出浓郁的中国传统工艺特色,反映了当时建筑技术的科技水平。本研究从血料灰浆的科技史入手,综述了传统血料灰浆的应用历史和制备方法,包括在油饰彩画地仗层、油漆地仗层、漆器和桥梁建筑等方面;结合各种现代科技文献评述了古代建筑灰浆中动物血蛋白的检测方法,包括各种物理化学方法和免疫法;阐述了灰浆中动物血的功能,如加气作用、减水作用、防水作用、平整和抗龟裂作用等,探讨了血料灰浆的作用机理。此外,还简述了血料、蛋清、糯米、红糖、桐油等有机添加剂的复配问题。本研究的总体目标是希望以此为基础,进一步加深对血料灰浆科学性和局限性的认识,并通过对血料灰浆的研究和传统工艺的科学化改进,更好地为当今古建筑修缮保护服务。

    Abstract:

    An organicinorganic mortar can be created by adding organic materials to lime mortars and tabia. Blood based mortar is one of the most important representative formulations among the ancient Chinese organicinorganic mortars. It reflects not only a distinctive feature of traditional Chinese crafts, but also the scientific level of the construction technology at that time. The history of use of bloodmaterial mortar can be traced back 2200years, to the ground plaster used in building the Qin (B.C.221~ 206) Xianyang Palace, which consisted of pig blood, lime and a kind of stone named ginger rock. This bloodbased mortar was used primarily as the ground layer of decorative oil paintings, lacquer ware, etc. It is generally believed that the widest use of blood based material as a ground layer of decorative oil paintings and oil paint was in the Qing Dynasty (A.D.1644~1911), while its use in lacquerware starts no later than the Ming Dynasty (A.D.1368 1644). The method for preparing bloodbased mortar, which originates in the Qin consists of rubbing, filtering, adding limewater, and stirring. The ultimate product is jellylike. It can be used directly, or it can be first prepared with lime and then put into use. Nowadays the analysis and detection of the blood products in mortars is based primarily on the detection of the proteins in the mortars. The detection methods include Kjeldahl determination, spectroscopic analysis, chromatographic study, mass spectrometric method, Folinphenol method and ELISA method, etc. Animal blood exerts many effects on mortars, including foaming, water reduction, improved viscosity, waterproofing, decrease of roughness, anticracking, etc. This article also discusses the effective mechanisms of bloodbased mortar. The foaming effect comes from the proteins contained in the animal blood, especially the hemoglobin which has a great solubility and makes a perfect foaming agent.The water reducing effect is due to the anionic and hydrophilic groups of the blood proteins enhancing the dispersion of particles in the mortar, thus releases the free water in the flocculated structure. The improved viscosity due to the blood protein is probably caused by the ion crosslinking of calcium, carbonate and hydroxyl ions in the alkaline environment created by the lime. Waterproofing results from chemical bonds formed by the hydroxyl, amino and carboxyl groups, etc. Finally, the mixture of blood materials and tung oil forms channelstructured membrane, thus improves roughness and reduces cracking Apart from bloodbased mortars, the ancient Chinese organicinorganic mortars also utilized eggwhites, sticky rice, brown sugar and tung oil, etc. These mortars, like bloodbased mortar, also had excellent properties and functions. In many cases, all five natural organic compounds (egg white, blood, sticky rice, brown sugar and tung oil) are mixed up with one another to form integrated mortars. The overall objective was to learn more about the scientific basis and limitations of bloodmaterial mortars to aid in historical building restoration and protection.

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  • 收稿日期:2012-01-13
  • 最后修改日期:2012-07-28
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  • 在线发布日期: 2013-05-20
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