基于水凝胶方法的重庆地区鎏金青铜器除锈新技术研究
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(1.重庆市文化遗产研究院,重庆 400013;2.丰都县文物管理所,重庆 408200;3.重庆中国三峡博物馆,重庆 400013;4.陕西师范大学化学与材料科学学院,陕西西安 710062)

作者简介:

杨小刚(1974—),男, 2012年博士毕业于西北大学,研究馆员,研究方向为文物保护,E-mail: 654318159@qq.com

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中央高校基本科研业务费专项资金资助(GK201902014),重庆市社会科学规划课题资助(2013YBLS114)


Using hydrogels to remove rust from gilt bronzes in the Chongqing area
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(1. Chongqing Cultural Heritage Research Institute, Chongqing, 400013, China;2. Fengdu County Cultural Relics Management Office, Chongqing 408200, China;3. Chongqing China Three Gorges Museum, Chongqing, 400013, China;4. School of Chemistry and Materials Science, Shaanxi Normal University, Xi’an 710062, China)

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    摘要:

    中国汞齐鎏金技术起源于战国之前,该技术的出现极大地提升了青铜器的可观赏性和耐腐蚀性,给东周青铜文化带了一股新气象。鎏金青铜器由于长期埋藏于地下环境之中,出土后往往被一层坚硬的锈蚀物所覆盖,严重影响了文物外观,也不利于文物的保存。目前,鎏金青铜器除锈方法主要有化学湿法除锈,激光物理除锈,机械除锈法等方法。本研究依据鎏金青铜器腐蚀特点,采用复合水凝胶体系构建鎏金青铜器除锈新方法,以丙烯酸和聚乙烯醇为成胶剂,以弱酸性的甲酸和半胱氨酸为清洗组分的复合凝胶清洗剂。实施案例显示:该凝胶除锈剂可以实现对覆盖于鎏金层之上的赤铜矿、孔雀石和蓝铜矿等铜锈的高效去除,不污染文物表面,适用于复杂表面清洗,能够减少湿法清洗中清洗剂在鎏金层中扩散而产生的腐蚀破坏,符合文物保护“最小介入”与“不改变文物外貌”的原则要求。

    Abstract:

    The technology of amalgamation and gilding in China originated before the Warring States period and greatly improved the ornamental value and corrosion resistance of bronzes, thus bringing a new atmosphere to the bronze culture of the Eastern Zhou Dynasty. Due to long-time underground burial, gilt bronze wares are often found, after excavation, covered with a hard layer of soil rust, which seriously affects their appearance and subsequent stabilization treatments. At present, methods of removing rust from gilt bronze wares include wet chemical, laser ablation and mechanical methods, all of which have some problems. Based on corrosion characteristics of gilt bronzes, we created a new method for removal of rust based on a composite hydrogel system, where acrylic acid and polyvinyl alcohol act as gelling agents, and solutions of weakly acidic formic acid and cysteine are used for washing. Implementation of this method shows that it can remove the rust (i.e, cuprite, malachite and azurite) from the gilding layer efficiently without damaging the surfaces of cultural relics. This method is suitable for cleaning complicated surfaces, in that it can reduce corrosion damage and also conforms to the principle and requirement of “minimal intervention” and “not changing appearance” for cultural relic conservation.

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历史
  • 收稿日期:2018-03-09
  • 最后修改日期:2018-11-01
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  • 在线发布日期: 2019-03-20
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