琼脂凝胶在青铜文物激光清洗中的应用研究
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(馆藏文物保存环境国家文物局重点科研基地(上海博物馆),上海博物馆文物保护科技中心,上海 200231)

作者简介:

沈依嘉(1982—),女,2015年毕业于意大利文物保护与修复高级研究院(Istituto Superiore per la Conservazione ed il Restauro),陶瓷、玻璃、金属及有机质文物保护与修复专业,硕士,助理馆员,E-mail: shenyijia@shanghai-museum.org

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上海市科研计划项目资助(17DZ1205100)


Applied research on the agar gel-mediated laser cleaning of bronze objects
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(Key Scientific Research Base of Museum Environment (Shanghai Museum), State Administration for Cultural Heritage, Conservation Center of Shanghai Museum, Shanghai 200231, China)

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    摘要:

    激光清洗应用于青铜文物上有时会使其表面颜色及其他一些物化性质发生改变。如何优化这种方法改善这种状况?为此,本工作将琼脂凝胶-激光联用作为一种可能的优化手段,首先研究了凝胶对激光能量和作用的影响,包括以能量计测量激光穿过凝胶层后的能量减弱幅度,以及通过热敏纸和文物样品上的烧蚀斑观察凝胶对激光烧蚀结果的影响。其次在不同类型的青铜文物样品上将之与普通湿法激光清洗、机械清洗等手段做清洗效果的对比实验,并以视频显微镜、扫描电镜及能谱仪、X射线衍射等手段进行分析验证。实验结果发现,凝胶能小幅度降低激光能量,减轻激光引起的青铜文物表面微观结构的改变,为清洗操作提供更灵活多样的选择。凝胶-激光联用的方法在实验的文物样品上取得了理想的清洗效果,兼顾了操作的效率性和安全性,是在今后的应用中可被考虑的手段。

    Abstract:

    Laser cleaning can cause color changes and other modifications of the physical-chemical properties of bronze surfaces. The paper studied the agar gel-mediated laser cleaning with the aim of optimizing the cleaning effects. First, we conducted research on how the gel influences laser energy and its ablation mechanism by measuring the energy attenuation of laser passing through gel sheets and carrying out ablation tests on bronze samples as well as on heat-sensitive paper. Then, cleaning experiments were done on bronze samples to compare the cleaning effectiveness of the gel-mediated method with that of wet laser cleaning and mechanical cleaning. Video microscopy, scanning electron microscopy, energy-dispersive X-ray spectrometry and X-ray diffraction were used for evaluation. The results demonstrate that the gel could bring moderate attenuation to laser energy and thus reduce the micro-structural modifications, making cleaning operations more versatile. With efficacy and safety requirements balanced, it is concluded that the gel-mediated method optimizes cleaning effects and has potential in the future applications.

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  • 收稿日期:2018-01-08
  • 最后修改日期:2018-03-02
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  • 在线发布日期: 2018-07-13
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