丙烯酸酯改性明胶古墨锭修补胶的试验研究
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(1.南京航空航天大学材料科学与技术学院文物保护材料研究所,江苏南京 210016;2.上海博物馆文物保护与考古科学实验室, 上海 200050)

作者简介:

邱建辉(1949—),男,1977年毕业于南京化工学院,高工,硕士研究生导师。E mail:qjhnj@nuaa.edu.cn

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上海博物馆科研计划资助(2006001)


Study of acrylonitrile and butyl acrylate modified gelatin adhesives to repair ancient ink sticks
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(1.Institute of Cultural Relics Protection Material,College of Material Science and Technology,Nanjing University of Aeronautics and Astronautics,Nanjing 210016,China;2.The Research Laboratory for Conservation and Archceology,Shanghai Museum,Shanghai 200050,China)

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    摘要:

    墨是中华民族的一颗瑰宝,然而随着时光的流逝,墨锭霉变、破损开裂、粉化酥解,而难以长久保存,刻不容缓需要保护。为此,采用反相乳液接枝的方法,用丙烯酸丁酯、丙烯腈对明胶接枝改性;分析了接枝改性的反应温度、反应时间、单体用量、预处理时间等对接枝反应的影响,并用FTIR进行表征;分别进行干热加速老化试验前后的剪切强度、劈裂强度、抗弯强度等性能测试。经过模拟粘接和试验性修补结果表明,用丙烯酸丁酯、丙烯腈对明胶接枝改性胶的剪切强度0.44MPa、劈裂强度68N/m、抗弯强度69N/m,加速老化后仍分别保持0.37MPa、54N/m和44N/m。修复后的古墨锭,粘接强度高、防霉抗菌、耐老化、无损伤,对古墨锭的加固保护效果明显。

    Abstract:

    Ink sticks are one of the Chinese nation's treasures.However,as time goes by,most of them have mildewed,cracked,fractured,powdered and crumbled.It is difficult to preserve ink sticks for a long time,and protection and repair are urgently needed.The gelatin graft copolymer was synthesized by inverse emulsion polymerization with butyl acrylate (BA) and acrylonitrile (AN).Experimental parameters such as pretreatment time,monomer dosage,reacting temperature and times were investigated.The shear,the bending,and cleavage strengths,before and after accelerated aging,and resistance,were tested.The GEL/BA/AN graft copolymer was characterized by FTIR.In simulated repair tests,the shear,bending and cleavage strengths of samples adhered with gelatin-acrylonitrile butyl acrylate adhesive were found to be 0.44MPa,68 N/m and 69 N/m respectively; after accelerated aging,they were 0.37MPa,54 N/m and 44 N/m respectively.The results indicate that the restored ink-sticks have high bond strength.The method is also antibacterial,anti-fungal,anti aging and non destructive.It is an effective reinforcement and conservation method for ancient ink sticks.

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  • 收稿日期:2009-02-22
  • 最后修改日期:2009-05-04
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  • 在线发布日期: 2019-07-16
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