薄荷醇加固对武王墩墓出土竹席碳十四年代测定的影响
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(1.国家文物局考古研究中心,北京 100013;2.国家文物局考古研究中心与北京大学考古文博学院考古年代学联合实验室,北京 100871;3.国家文物局考古研究中心与中国林业科学院木材工业研究所木材考古联合实验室,北京 100091;4.兰州大学化学化工学院,甘肃兰州 730000;5.北京大学考古文博学院,北京 100871;6.安徽省文物考古研究所,安徽合肥 230601)

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闫 欣(1988—)女,2021年博士毕业于以色列魏茨曼科学研究所,馆员,研究方向为碳十四年代学,E-mail: yanxin1018@163.com 通信作者:张治国(1978—)男,博士,研究馆员,E-mail: zzgwys@126.com

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Influence of menthol consolidation on the radiocarbon dating of bamboo mat excavated from Wuwangdun Tomb
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(1. National Centre for Archaeology, Beijing 100013, China;2. Joint Laboratory for Archaeological Chronology by National Centre for Archaeology and School of Archaeology and Museology, Peking University, Beijing 100871, China;3. Joint Laboratory of Wood Archaeology by National Centre for Archaeology and Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, China;4. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China;5. School of Archaeology and Museology, Peking University, Beijing 100871, China;6. Anhui Provincial Institute of Cultural Relics and Archaeology, Hefei 230601, China)

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    摘要:

    薄荷醇是一种新兴的保护加固材料,可应用于考古发掘现场脆弱文物的提取。但薄荷醇作为含碳的有机材料,若残留在样品中可能对碳十四测年产生影响。在对安徽淮南武王墩墓出土竹席的碳十四年代研究中,定性和定量的分析结果均显示,经过碳十四测年常用的“酸-碱-酸”流程处理后,曾用作临时固型的薄荷醇在竹席样品中仍有残留,这可以通过核磁共振氢谱检出,并导致测年结果偏年轻。虽然放置更长时间、或采取纤维素提取的方式处理可以消除这种影响,得出在加速器质谱约0.3%的检测精度上与未经薄荷醇加固的竹席样品一致的年代,但是仍然建议对有测年需求的样品,应在使用有机试剂之前进行测年采样,以避免不必要的污染。

    Abstract:

    Menthol is a newly developed material for temporary consolidation and can be applied during the extraction of fragile artifacts at archaeological excavation sites. However, as an organic reagent, residual menthol incorporated into samples may affect radiocarbon dating results. In radiocarbon dating experiments conducted on bamboo mat excavated from Wuwangdun Tomb in Huainan, Anhui Province, both qualitative and quantitative analyses demonstrated that menthol residues still remained in the samples even after the routine Acid-Base-Acid treatment used for radiocarbon dating. The residual menthol was identified by 1H NMR analysis and was found to produce artificially younger radiocarbon ages. The study further showed that this influence could be eliminated either by allowing a longer interval before dating or by applying cellulose extraction treatment, thereby yielding radiocarbon ages consistent with untreated bamboo samples. Nevertheless, to avoid unnecessary complication, it is recommended that samples intended for radiocarbon dating be taken prior to the application of organic conservation reagents.

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闫欣,汪嘉君,贺天宇,吴小红,方玲,张治国.薄荷醇加固对武王墩墓出土竹席碳十四年代测定的影响[J].文物保护与考古科学,2026,(3):174-182.

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  • 收稿日期:2024-08-08
  • 最后修改日期:2025-10-28
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  • 在线发布日期: 2026-07-13
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