基于乙二醛脱水漆器漆膜胶黏剂的制备及性能研究
CSTR:
作者:
作者单位:

(1.湖北省文物考古研究院,湖北武汉 430077;2.湖北省博物馆,湖北武汉 430077;3.阳新县博物馆,湖北黄石 435200)

作者简介:

陈子繁(1984—),男,副研究馆员,研究方向为有机质文物保护,E-mail: 13931236@qq.com

通讯作者:

中图分类号:

基金项目:

国家文物局文物科学技术研究项目(自筹)(2023ZCK020)资助


Preparation and performance evaluation of a lacquer film adhesive for glyoxal-dehydrated lacquerware
Author:
Affiliation:

(1. Hubei Provincial Institute of Cultural Relics and Archaeology, Wuhan 430077, China;2. Hubei Provincial Museum, Wuhan 430077, China;3. Yangxin County Museum, Huangshi 435200, China)

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    出土饱水木质漆器的保护与修复是文保领域的重大挑战之一。虽然乙二醛复合液脱水技术已成为该类文物定型加固的主流方法,成功解决了器物整体脱水定形的难题,但该工艺不可避免地引入了次生病害风险:脱水过程中因木胎与漆膜收缩率差异导致的漆膜起翘、开裂与脱落,以及乙二醛残留所引发的持续性弱酸性环境(pH≈4~5)。这种酸性微环境严重抑制了传统生漆胶黏剂中漆酶的活性,导致黏结强度大幅衰减,耐久性受损。本研究旨在解决上述核心痛点,开发一种专用于乙二醛脱水漆器修复的新型复合胶黏剂。研究以湖北恩施天然生漆为基体,以复合非离子表面活性剂Tween-20、大豆分离蛋白(SPI)和纳米SiO2制备新型漆膜胶黏剂。通过正交试验优化配方,确定最佳配方。性能测试表明:配方胶黏剂剪切黏结强度达3.8 MPa,较纯生漆提高约58%;在pH≈4弱酸环境中浸泡30 d后强度保留率达91%,显著高于纯生漆的65%;50℃/95%RH高温高湿条件下30 d增重仅1.0%,无霉变(纯生漆分别为+3.0%并出现轻微霉斑);固化漆膜色差ΔE约2.0,肉眼难以察觉颜色变化。文物修复实践验证了新胶黏剂在脱落漆膜回贴中的可行性:修复后的漆膜贴合紧密、色泽一致,未见返翘再脱落现象。该研究成果为乙二醛脱水漆器的粘接修复提供了新型材料方案,也为传统漆工艺与现代功能材料的结合提供了参考。

    Abstract:

    The conservation and restoration of excavated waterlogged lacquered wooden artifacts remain major challenges in the field of cultural heritage preservation. Although the glyoxal composite dehydration technology has become a mainstream method for the stabilization and reinforcement of such artifacts, effectively addressing dimensional stabilization during dehydration, it also inevitably introduces risks of secondary deterioration. These include lacquer film cracking, warping and detachment caused by differential shrinkage between the wooden substrate and the lacquer layer, as well as persistent weakly acidic conditions (pH≈4-5) resulting from residual glyoxal. Such acidic environments significantly inhibit the activity of laccase involved in the oxidative polymerization of raw lacquer, thereby reducing the bonding strength and durability of traditional lacquer adhesives. To address these issues, this study developed a novel composite adhesive specifically designed for the restoration of glyoxal-dehydrated lacquerware. Natural raw lacquer from Enshi, Hubei Province, was used as the base material, while Tween-20, soy protein isolate (SPI) and nano-SiO2 were introduced as functional modifiers. An orthogonal experimental design was employed to optimize the formulation. The performance evaluation demonstrated that the optimized adhesive achieved a shear bonding strength of 3.8 MPa, representing an increase of approximately 58% compared with pure raw lacquer. After immersion in a weakly acidic environment (pH≈4) for 30 days, the adhesive retained 91% of its original strength, significantly higher than the 65% retention observed for pure lacquer. Under accelerated aging conditions of 50℃ and 95% relative humidity (RH) for 30 days, the composite adhesive exhibited only a 1.0% weight increase without visible mold growth, whereas pure lacquer showed a 3.0% increase accomplished by slight mildew formation. The cured adhesive film also exhibited excellent chromatic stability, with a color difference (ΔE) of approximately 2.0, which was nearly imperceptible to the naked eye. The practical conservation treatment of excavated lacquerware further verified the feasibility of the adhesive for reattaching detached lacquer films. The restored lacquer layers exhibited strong adhesion, stable morphology, and good chromatic compatibility without secondary warping or delamination. This study provides a new material strategy for the conservation of glyoxal-dehydrated lacquerware and offers a useful reference for integrating traditional lacquer technique with modern functional materials in cultural heritage conservation.

    参考文献
    相似文献
    引证文献
引用本文

陈子繁,龚祥炜,祁筱菡,李俊.基于乙二醛脱水漆器漆膜胶黏剂的制备及性能研究[J].文物保护与考古科学,2026,(3):47-56.

复制
分享
相关视频

文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2025-11-25
  • 最后修改日期:2026-04-16
  • 录用日期:
  • 在线发布日期: 2026-07-13
  • 出版日期:
文章二维码
您是第位访问者
主办单位:上海博物馆 编辑出版:《文物保护与考古科学》编辑委员会
地址:上海市徐汇区龙吴路1118号,上海博物馆文物保护科技中心,《文物保护与考古科学》编辑部
电话:021-54362886 传真:021-54363740 E-mail:wwbhykgkx@163.com
文物保护与考古科学 ® 2026 版权所有
沪ICP备10003390号-3
沪公网安备 31010102005301号