山东省兰陵县塔山墓地出土青膏泥性能分析
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(1.山东省文物考古研究院,山东济南 250000;2.中国科学院上海硅酸盐研究所,上海 200050;3.上海理工大学材料与化学学院,上海 200093)

作者简介:

王春云(1984—),男,副研究馆员,研究方向为战汉考古,E-mail: skgyywb@163.com 通信作者:赵 静(1981—),女,正高级工程师,研究方向为脆弱硅酸盐质文化遗产保护,E-mail: zhaojing@mail.sic.ac.cn

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基金项目:

上海市自然科学基金项目(No.23ZR1421000)、硅酸盐质文物保护教育部重点实验室重点课题项目(SCRC2023KF01ZD)资助


Properties analysis of Qinggaoni unearthed from the Lanling Tashan tombs in Shandong Province
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(1. Shandong Provincial Institute of Cultural Relics and Archaeology, Jinan 250000, China;2. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;3. School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China)

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    摘要:

    青膏泥是考古发掘中常见的物质,在墓葬坑中放置青膏泥用于密封的做法源于新石器时代,商代开始流行,盛行于周汉时期并于秦汉时期达到顶峰。但是关于青膏泥的研究相对较少,尤其是其中影响青膏泥结构组成的腐殖质等的研究鲜有报道。本研究针对山东省兰陵县塔山墓地几个墓葬发掘出土的青膏泥样品,采用激光粒度仪、扫描电子显微镜-能谱仪、傅里叶变换红外光谱仪等测试分析青膏泥样品的粒径、显微形貌、组成结构,以及有机质中腐殖质的性能。研究结果表明:青膏泥中的无机矿物主要包含石英、钠长石、白云母、羟基氧化铁、水铁矿和黑云母,这些矿物具有较大的比表面积和表面电荷,与有机腐殖质中含量较高、且和矿物质结合最紧密的胡敏素,以及具有胶体特性的胡敏酸等腐殖质进行结合而形成稳定的无机-有机复合体;其中墓地M166出土的青膏泥样品颗粒比表面积较大,粒径分布较为集中,表面同时富集的蜡样芽孢杆菌等微生物,也为青膏泥中腐殖质的形成提供了条件。

    Abstract:

    i>Qinggaoni is a common material in archaeological explorations. The practice of placing Qinggaoni in burial pits for sealing purposes originated in the Neolithic Age, gained popularity in the Shang Dynasty, prevailed from the Zhou to Han Dynasties, and reached its peak in the Qin and Han Dynasties. However, relatively few studies have focused on Qinggaoni, especially on humus, which affects the structural properties of Qinggaoni. In this study, a synchronous laser diffraction and dynamic image particle analyzer (LDPA), a scanning electron microscope equipped with an energy dispersive spectrometer (SEM-EDS) and a Fourier transform infrared spectrometer (FTIR) were used to analyze the particle size, micromorphology, composition and humus properties of the Qinggaoni samples excavated from different sites in the Lanling Tashan tombs, Shandong Province. The results show that the inorganic minerals present in the Qinggaoni mainly include quartz, albite, muscovite, hydroxy-iron oxide, ferrihydrite and biotite. These minerals have a large specific surface area and surface charge, and they were combined with humin (which has a high content in organic humus and is closely bound to minerals) and humic acid (which has colloidal properties) to form a stable inorganic-organic complex. Among the samples, those from Tomb M166 show a large specific surface area and broader particle size distribution. Microorganisms such as Bacillus cereus are also enriched on the surface, providing favorable conditions for the formation of humus in the paste.

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王春云,赵萌,张艳群,赵静,安明晖,LEE Soo Bin,李强,罗宏杰.山东省兰陵县塔山墓地出土青膏泥性能分析[J].文物保护与考古科学,2026,(2):175-184.

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  • 收稿日期:2024-09-03
  • 最后修改日期:2025-03-04
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  • 在线发布日期: 2026-05-12
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