The object of our study was the “Huangyan Shabu Kiln Sites” in Zhejiang province. We investigated the Shabu Sites and the surrounding areas and also took some typical celadon samples through archaeological field surveys. We then used archaeometric methods to study the product characteristics, porcelain-making technologies, and the production time of the kilns. The internal structures of the body and glaze of the celadons unearthed from Huangyan were analyzed by optical microscopy. The chronological age of these typical celadon samples was determined using thermoluminescence. The chemical compositions of the body and glaze of samples from both Huangyan and Shanglin Lake were determined by energy dispersive X-ray fluorescence (EDXRF) and compared. In addition, by comparative study of the characteristics of Yue ware, we found the samples from the Huangyan Kiln were basically in line with the products of Yue ware system, in terms of raw materials, fuels, furnace structures, shape features, decorative arts and processing technologies. The study results show that the Huangyan Shabu Kilns in Zhejiang province are important kiln remains dating from the late Tang Dynasty to the Southern Song Dynasty. They belong to Yue ware system and show high ceramic-firing skills and significant archaeological research values.