还原气氛下低温等离子体去除青铜粉状锈的初步研究
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(1.江苏科技大学科学技术史研究所,江苏镇江 212100;2.中国科学技术大学先进技术研究院,安徽合肥 230031;3.山西省考古研究院,山西太原 030001;4.青岛市文物保护与考古研究所,山东青岛 266000;5.中国科学院等离子体物理研究所,安徽合肥 230031)

作者简介:

龚钰轩(1985—),女,2016年毕业于中国科学技术大学科学技术史专业,副教授,研究方向为文化遗产保护与科技考古,E-mail: 104808507@qq.com

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国家重点研发计划(2020YFC1522000)资助,安徽省重点研究与开发计划项目(2022o07020002)资助


Preliminary study on removal of powdery bronze rust by low temperature plasma in a reducing atmosphere
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(1. Institute of History of Science and Technology, Jiangsu University of Science and Technology, Zhenjiang 212100, China;2. Institute of Advanced Technology, University of Science and Technology of China, Hefei 230031, China;3. Shanxi Provincial Institute of Archaeology, Taiyuan 030001, China;4. Qingdao Institute of Cultural Relics Conservation and Archaeology, Qingdao 266000, China;5. Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031, China)

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    摘要:

    青铜器是金属类文物的重要组成部分,具有极高的历史价值、艺术价值和科学价值。然而由于青铜器自身材质的特性,加之受埋藏环境因素的影响,考古发掘出土的青铜器文物大多锈蚀严重。青铜器的锈蚀主要可分为有害锈和无害锈,无害锈比较稳定对青铜器文物相对无害。而“粉状锈”作为一种对青铜器危害极大的有害锈,其会使青铜器文物酥粉、糟朽,严重影响文物的保存寿命。同时粉状锈还具有一定的传播力,可在青铜器文物自身和青铜器文物间造成损害。因此,本研究首次尝试将低温等离子体技术引入青铜器粉状锈的去除研究中,通过电化学腐蚀制备表面附着粉状锈的青铜样品,并于还原气氛下对样品进行低温等离子体处理,进而通过对比处理前后青铜样品的表征数据,证明低温等离子体技术对去除粉状锈中Cl离子的有效性,以期为青铜器文物保护提供新的思路和方法。

    Abstract:

    Bronze ware, having high historical, artistic and scientific value, plays an important role in metal cultural relics. However, due to the characteristics of natural materials themselves and the influence of the burial environment, most bronze artifacts unearthed from archaeological sites or cemeteries have been seriously degraded and corroded. The corrosion of bronze ware can be divided into two types—harmful rust and harmless rust; the latter is relatively stable and harmless to bronze artifacts. However, “powdery rust” is severely detrimental to bronzes, and can make the bronzes crumble and rot, thereby seriously affecting the life of the relics. Furthermore, powdery rust also has a certain spreading power, which can cause damage to the bronze relics themselves and the neighboring ones. Therefore, we attempted for the first time to introduce low-temperature plasma technology as a means of removing powdery rust from bronzes. Bronze samples with powdery rust on the surface were prepared by electrochemical corrosion. Then the samples were treated with low temperature plasma in a reducing atmosphere. Comparison of data of bronze samples before and after the treatment shows that the low-temperature plasma technology could effectively remove chloride ions in the powder rust. This study could provide a new idea and method for the conservation of bronze relics.

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  • 收稿日期:2023-05-30
  • 最后修改日期:2024-06-19
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  • 在线发布日期: 2024-12-30
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